Robust synthesis of green fuels from biomass-derived ethyl esters over a hierarchically core/shell-structured ZSM-5@(Co/SiO2) catalyst

Darui Wang; Bo Wang; Yu Ding; Qingqing Yuan; Haihong Wu; Yejun Guan; Peng Wu

doi:10.1039/C7CC05007K

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Robust synthesis of green fuels from biomass-derived ethyl esters over a hierarchically core/shell-structured ZSM-5@(Co/SiO₂) catalyst†

Darui Wang,^ab Bo Wang,^a Yu Ding,^a Qingqing Yuan,^a Haihong Wu,^a Yejun Guan

*^a and Peng Wu

*^a

Author affiliations

* Corresponding authors

^a Shanghai Key Laboratory of Green Chemistry and Chemical Process, School of Chemistry and Molecular Engineering, East China Normal University, North Zhongshan Rd. 3663, Shanghai 200062, China
E-mail: pwu@chem.ecnu.edu.cn, yjguan@chem.ecnu.edu.cn

^b State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201208, China

Abstract

A novel bifunctional ZSM-5@(Co/SiO₂) material with a hierarchical core/shell structure was successfully prepared through a simple chemoselective interaction between the crystal surface silica species of zeolite and the external Co²⁺ source in basic media, which served as an excellent catalyst in the synthesis of green fuels from biomass-derived ethyl esters.

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Article information

DOI: https://doi.org/10.1039/C7CC05007K
Article type: Communication
Submitted: 28 Jun 2017
Accepted: 23 Aug 2017
First published: 23 Aug 2017

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Chem. Commun., 2017,53, 10172-10175

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Robust synthesis of green fuels from biomass-derived ethyl esters over a hierarchically core/shell-structured ZSM-5@(Co/SiO₂) catalyst

D. Wang, B. Wang, Y. Ding, Q. Yuan, H. Wu, Y. Guan and P. Wu, Chem. Commun., 2017, 53, 10172 DOI: 10.1039/C7CC05007K

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