Mechano-, thermo-, solvato-, and vapochromism in bis(acetato-κ1O)[4′-(4-(diphenylamino)phenyl)](2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II) and its polymer

Takamasa Tsukamoto; Risa Aoki; Ryota Sakamoto; Ryojun Toyoda; Masaki Shimada; Yohei Hattori; Yasutaka Kitagawa; Eiji Nishibori; Masayoshi Nakano; Hiroshi Nishihara

doi:10.1039/C7CC05022D

Mechano-, thermo-, solvato-, and vapochromism in bis(acetato-κ¹O)[4′-(4-(diphenylamino)phenyl)](2,2′:6′,2′′-terpyridine-κ³N,N′,N′′)zinc(ii) and its polymer†

Takamasa Tsukamoto,^a Risa Aoki,^a Ryota Sakamoto,

*^ab Ryojun Toyoda,^a Masaki Shimada,^a Yohei Hattori,^a Yasutaka Kitagawa,^c Eiji Nishibori,^d Masayoshi Nakano

^c and Hiroshi Nishihara*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: sakamoto@chem.s.u-tokyo.ac.jp, nisihara@chem.s.u-tokyo.ac.jp

^b JST-PRESTO, 4-1-8, Honcho, Kawaguchi, Saitama 332-0012, Japan

^c Division of Chemical Engineering, Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan

^d Division of Physics, Faculty of Pure and Applied Science, Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), and Center for Integrated Research in Fundamental Science and Engineering (CiRfSE), University of Tsukuba, 1-1-1, Tennodai, Tsukuba, Ibaraki 305-8571, Japan

Abstract

The titled complex exhibits multi-functional luminochromism in the solid state, despite its simple chemical structure. The complex shows solid-state vapochromism and mechanochromism. The polymer analogue of the complex undergoes solvatochromism and thermochromism.

Chemical Communications

Mechano-, thermo-, solvato-, and vapochromism in bis(acetato-κ¹O)[4′-(4-(diphenylamino)phenyl)](2,2′:6′,2′′-terpyridine-κ³N,N′,N′′)zinc(ii) and its polymer†

Abstract

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Mechano-, thermo-, solvato-, and vapochromism in bis(acetato-κ¹O)[4′-(4-(diphenylamino)phenyl)](2,2′:6′,2′′-terpyridine-κ³N,N′,N′′)zinc(II) and its polymer

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