Metallosupramolecular 3D assembly of dimetallic Zn4[RuL2]2 and trimetallic Fe2Zn2[RuL2]2

Abstract

A novel metallo-organic ligand [RuL₂] with four uncomplexed coordination sites was created, and upon treatment with Zn²⁺ generated a dimetallic 3D metallosupramolecule in nearly quantitative yield. This self-assembly process gave stable intermediates, opening the pathway to the first 3D metallo-assembly possessing two Ru²⁺, two Fe²⁺, and two Zn²⁺ ions precisely located in the different edges. This strategy opens the door to novel designer 3D polymetallic constructs capable of diverse applications.