Issue 84, 2017
From the journal:

Chemical Communications

Cooperative self-assembly and gelation of organogold(i) complexes via hydrogen bonding and aurophilic Au⋯Au interactions†

Jiangjun Chen,a   Zhongxin Zhang,a   Chengming Wang,b   Zhao Gao,a   Zongchun Gaoa  and  Feng Wang ORCID logo *ac  

* Corresponding authors

a Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, China
E-mail: drfwang@ustc.edu.cn
Fax: +86 551 3606 095

b Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China

c State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Abstract

With the synergistic combination of intermolecular Au(I)–Au(I) and hydrogen bonding interactions, a rod–coil alkynyl–gold(I)–isocyanide monomer tends to form supramolecular fibers and gels via a cooperative nucleation–elongation self-assembly mechanism, which display Ag(I) ion-triggered responsiveness.

Graphical abstract: Cooperative self-assembly and gelation of organogold(i) complexes via hydrogen bonding and aurophilic Au⋯Au interactions

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Article information

DOI
https://doi.org/10.1039/C7CC05613C
Article type
Communication
Submitted
19 Jul 2017
Accepted
27 Sep 2017
First published
27 Sep 2017

Chem. Commun., 2017,53, 11552-11555

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Cooperative self-assembly and gelation of organogold(I) complexes via hydrogen bonding and aurophilic Au⋯Au interactions

J. Chen, Z. Zhang, C. Wang, Z. Gao, Z. Gao and F. Wang, Chem. Commun., 2017, 53, 11552 DOI: 10.1039/C7CC05613C

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