Issue 78, 2017

A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

Abstract

Crystals of a hydrated Pu(III) chloride, (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)5] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.

Graphical abstract: A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

Supplementary files

Article information

Article type
Communication
Submitted
02 Aug 2017
Accepted
12 Sep 2017
First published
12 Sep 2017

Chem. Commun., 2017,53, 10816-10819

A new Pu(III) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

R. G. Surbella, L. C. Ducati, K. L. Pellegrini, B. K. McNamara, J. Autschbach, J. M. Schwantes and C. L. Cahill, Chem. Commun., 2017, 53, 10816 DOI: 10.1039/C7CC05988D

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