Issue 71, 2017
From the journal:

Chemical Communications

Tuning photochemical properties of phosphorus(v) porphyrin photosensitizers†

Ivan N. Meshkov, ORCID logo ab   Véronique Bulach,a   Yulia G. Gorbunova, ORCID logo *bc   Fedor E. Gostev,d   Victor A. Nadtochenko,d   Aslan Yu. Tsivadzebc  and  Mir Wais Hosseini ORCID logo *a  

* Corresponding authors

a Molecular Tectonics Laboratory, UMR UDS-CNRS, 7140 & icFRC, Université de Strasbourg, Strasbourg, France
E-mail: hosseini@unistra.fr

b A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky pr. 31-4, Moscow, Russia
E-mail: yulia@igic.ras.ru

c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky pr. 31, Moscow, Russia

d Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygina st. 4, Moscow, Russia

Abstract

Photosensitizing and emission properties of P(V) porphyrins were studied. The nature of the axial ligands, occupying the apical position on the P centre adopting an octahedral coordination geometry, strongly influences singlet oxygen generation and charge transfer and allows switching between the two processes.

Graphical abstract: Tuning photochemical properties of phosphorus(v) porphyrin photosensitizers

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Article information

DOI
https://doi.org/10.1039/C7CC06052A
Article type
Communication
Submitted
02 Aug 2017
Accepted
15 Aug 2017
First published
15 Aug 2017
This article is Open Access
Creative Commons BY license

Chem. Commun., 2017,53, 9918-9921

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Tuning photochemical properties of phosphorus(V) porphyrin photosensitizers

I. N. Meshkov, V. Bulach, Y. G. Gorbunova, F. E. Gostev, V. A. Nadtochenko, A. Yu. Tsivadze and M. W. Hosseini, Chem. Commun., 2017, 53, 9918 DOI: 10.1039/C7CC06052A

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