Issue 81, 2017

Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids

Abstract

We present a study of the reactions of aldehydes in ionic liquids which gives evidence for the spontaneous formation of N-heterocyclic carbenes in ionic liquids based on 1,3-dialkyl substituted imidazolium cations from the lack of a deuterium isotope effect on the reaction of these ionic liquids with aldehydes.

Graphical abstract: Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids

Supplementary files

Article information

Article type
Communication
Submitted
04 Aug 2017
Accepted
04 Sep 2017
First published
04 Sep 2017

Chem. Commun., 2017,53, 11154-11156

Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids

N. M. A. N. Daud, E. Bakis, J. P. Hallett, C. C. Weber and T. Welton, Chem. Commun., 2017, 53, 11154 DOI: 10.1039/C7CC06112A

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