Issue 74, 2017
From the journal:

Chemical Communications

Unique structural micro-adjustments in a new benzothiadiazole-derived Zn(ii) metal organic framework via simple photochemical decarboxylation†

Xiao Han,a   Qing Cheng,a   Xiangru Meng,a   Zhichao Shao,a   Ke Ma,a   Donghui Wei, ORCID logo a   Jie Ding*a  and  Hongwei Hou ORCID logo *a  

* Corresponding authors

a College of Chemistry and Molecular Engineering, Zhengzhou University, Henan 450001, China
E-mail: houhongw@zzu.edu.cn, jieding@zzu.edu.cn

Abstract

The first example of micro-adjustments of a metal organic framework (MOF) structure was observed in a new Zn(II) MOF (Zn-BTDC-M1) derived from a benzothiadiazole-4,7-dicarboxylic acid (H2BTDC) ligand using a light-driven decarboxylation process. Interestingly, such decarboxylation occurs at the non-chelated wing of the ligand, which induced a change in the capability of the MOF for physical N2 adsorption and chemical NH3 gas adsorption.

Graphical abstract: Unique structural micro-adjustments in a new benzothiadiazole-derived Zn(ii) metal organic framework via simple photochemical decarboxylation

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Article information

DOI
https://doi.org/10.1039/C7CC06125K
Article type
Communication
Submitted
07 Aug 2017
Accepted
24 Aug 2017
First published
25 Aug 2017

Chem. Commun., 2017,53, 10314-10317

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Unique structural micro-adjustments in a new benzothiadiazole-derived Zn(II) metal organic framework via simple photochemical decarboxylation

X. Han, Q. Cheng, X. Meng, Z. Shao, K. Ma, D. Wei, J. Ding and H. Hou, Chem. Commun., 2017, 53, 10314 DOI: 10.1039/C7CC06125K

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