Issue 73, 2017

Tandem trifluoromethylthiolation/aryl migration of aryl alkynoates to trifluoromethylthiolated alkenes

Abstract

A trifluoromethylthiolation initiated aryl migration of aryl alkynoates was disclosed. This protocol employs AgSCF3 as the SCF3 source and MeCN as both the solvent and the hydrogen source. This provides a new access to trifluoromethylthiolated alkenes from readily available substrates and reagents.

Graphical abstract: Tandem trifluoromethylthiolation/aryl migration of aryl alkynoates to trifluoromethylthiolated alkenes

Supplementary files

Article information

Article type
Communication
Submitted
10 Aug 2017
Accepted
22 Aug 2017
First published
22 Aug 2017

Chem. Commun., 2017,53, 10136-10139

Tandem trifluoromethylthiolation/aryl migration of aryl alkynoates to trifluoromethylthiolated alkenes

H. Li, S. Liu, Y. Huang, X. Xu and F. Qing, Chem. Commun., 2017, 53, 10136 DOI: 10.1039/C7CC06232J

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