A new synthetic route to in-chain metallopolymers via copper(I) catalyzed azide–platinum–acetylide iClick

C. C. Beto; E. D. Holt; Y. Yang; I. Ghiviriga; K. S. Schanze; A. S. Veige

doi:10.1039/C7CC06289C

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A new synthetic route to in-chain metallopolymers via copper(i) catalyzed azide–platinum–acetylide iClick†

C. C. Beto,^a E. D. Holt,^ab Y. Yang,^ab I. Ghiviriga,^a K. S. Schanze

*^b and A. S. Veige

*^a

Author affiliations

* Corresponding authors

^a University of Florida, Department of Chemistry, Center for Catalysis, P. O. Box 117200, Gainesville, FL, USA
E-mail: veige@chem.ufl.edu

^b University of Texas at San Antonio, Department of Chemistry, One UTSA Circle, San Antonio, TX 78249, USA

Abstract

The first example of an in-chain metallo-poly(triazolate) synthesized by CuAAC is reported. Azido–platinum–acetylide (A–M–B) monomers are catalytically polymerized with copper(I) acetate to yield 1,2,3-triazolate linked Pt(II) units. The metallopolymers are characterized by multinuclear NMR, IR, UV/Vis, GPC, and MS.

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Article information

DOI: https://doi.org/10.1039/C7CC06289C
Article type: Communication
Submitted: 10 Aug 2017
Accepted: 11 Aug 2017
First published: 11 Aug 2017

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Chem. Commun., 2017,53, 9934-9937

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A new synthetic route to in-chain metallopolymers via copper(I) catalyzed azide–platinum–acetylide iClick

C. C. Beto, E. D. Holt, Y. Yang, I. Ghiviriga, K. S. Schanze and A. S. Veige, Chem. Commun., 2017, 53, 9934 DOI: 10.1039/C7CC06289C

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Chemical Communications

A new synthetic route to in-chain metallopolymers via copper(i) catalyzed azide–platinum–acetylide iClick†

Abstract

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A new synthetic route to in-chain metallopolymers via copper(I) catalyzed azide–platinum–acetylide iClick

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