A novel dinuclear Ni complex has been developed for the direct Mannich reaction of malonates with N-tosyl aryl imines with a low catalyst loading (0.1–0.05 mol%) on a preparative scale (5–50 mmol). The structure of the active species was verified via control experiments, ESI-HRMS, and DFT calculations.
S. Zhang, P. Deng, J. Zhou, M. Liu, G. Liang, Y. Xiong and H. Zhou, Chem. Commun., 2017, 53, 12914 DOI: 10.1039/C7CC06468C
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