The direct alkylheteroarylation of alkenes with cyclic and acyclic ethers via distal heteroaryl ipso-migration has been accomplished through the design of a photoredox-mediated C–H functionalization pathway. The use of inexpensive ethers as radical precursors combined with a straightforward method makes this a practical approach.
L. Gu, Y. Gao, X. Ai, C. Jin, Y. He, G. Li and M. Yuan, Chem. Commun., 2017, 53, 12946 DOI: 10.1039/C7CC06484E
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