Issue 85, 2017

A cluster-based mesoporous Ti-MOF with sodalite supercages

Abstract

The cooperative assembly of a hexagonal column shaped [Ti6O6][iPrO]66+ cluster and rhomboid Cu2I2 dimers using isonicotinic acid results in an unprecedented three-dimensional (3D) highly crystalline cluster-based Ti-MOF that features both giant sodalite cages with an inner diameter of 2.8 × 3.2 nm2 and 3D open square channels.

Graphical abstract: A cluster-based mesoporous Ti-MOF with sodalite supercages

Supplementary files

Article information

Article type
Communication
Submitted
24 Aug 2017
Accepted
01 Oct 2017
First published
02 Oct 2017

Chem. Commun., 2017,53, 11670-11673

A cluster-based mesoporous Ti-MOF with sodalite supercages

C. Wang, C. Liu, X. He and Z. Sun, Chem. Commun., 2017, 53, 11670 DOI: 10.1039/C7CC06652J

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