Issue 90, 2017
From the journal:

Chemical Communications

Intrinsic triple-emitting 2D copper thiolate coordination polymer as a ratiometric thermometer working over 400 K range†

Oleksandra Veselska, ORCID logo a   Darjan Podbevšek,b   Gilles Ledoux, ORCID logo b   Alexandra Fateeva ORCID logo c  and  Aude Demessence ORCID logo *a  

* Corresponding authors

a Univ Lyon, Université Claude Bernard Lyon 1, Institut de Recherches sur la Catalyse et l’environnement de Lyon (IRCELYON), UMR 5256 CNRS, Villeurbanne, France
E-mail: aude.demessence@ircelyon.univ-lyon1.fr

b Univ Lyon, Université Claude Bernard Lyon 1, Institut Lumière Matière (ILM), UMR CNRS 5306, Villeurbanne, France

c Univ Lyon, Université Claude Bernard Lyon 1, Laboratoire des Multimatériaux et Interfaces (LMI), UMR CNRS 5615, Villeurbanne, France

Abstract

A copper thiolate coordination polymer, [Cu(p-SPhCO2Me)]n, is described and exhibits, under UV, luminescence thermochromism, associated to a unique well-separated triple emission. This compound is the most promising candidate as a ratiometric temperature sensor, working in a wide temperature range, from 100 to 500 K, with a great sensitivity.

Graphical abstract: Intrinsic triple-emitting 2D copper thiolate coordination polymer as a ratiometric thermometer working over 400 K range

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Article information

DOI
https://doi.org/10.1039/C7CC06815H
Article type
Communication
Submitted
30 Aug 2017
Accepted
24 Oct 2017
First published
25 Oct 2017

Chem. Commun., 2017,53, 12225-12228

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Intrinsic triple-emitting 2D copper thiolate coordination polymer as a ratiometric thermometer working over 400 K range

O. Veselska, D. Podbevšek, G. Ledoux, A. Fateeva and A. Demessence, Chem. Commun., 2017, 53, 12225 DOI: 10.1039/C7CC06815H

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