Issue 80, 2017
From the journal:

Chemical Communications

Planar lithium silolide: aromaticity, with significant contribution of non-classical resonance structures†

Csaba Fekete,ab   Ilona Kovács,*a   László Nyulászi ORCID logo *ab  and  Tamás Holczbauerc  

* Corresponding authors

a Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Szt. Gellért tér 4, Budapest, Hungary
E-mail: ikovacs@mail.bme.hu

b MTA-BME Computation Driven Chemistry Research Group, Hungary
E-mail: nyulaszi@mail.bme.hu

c Institute of Organic Chemistry, Research Centre for Natural Sciences, Hungarian Academy of Sciences, POB. 206, H-1519 Budapest, Hungary

Abstract

The first planar lithium silolide characterized by X-ray crystallography is reported. The structural data, NMR and DFT results reveal high aromatic character, with the unusual dominance of non-classical resonance structures.

Graphical abstract: Planar lithium silolide: aromaticity, with significant contribution of non-classical resonance structures

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7CC07004G
Article type
Communication
Submitted
06 Sep 2017
Accepted
14 Sep 2017
First published
14 Sep 2017
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2017,53, 11064-11067

Permissions

Request permissions

Planar lithium silolide: aromaticity, with significant contribution of non-classical resonance structures

C. Fekete, I. Kovács, L. Nyulászi and T. Holczbauer, Chem. Commun., 2017, 53, 11064 DOI: 10.1039/C7CC07004G

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements