Photolysis of polymeric self-assembly controlled by donor–acceptor interaction

Tingjuan Qian; Feiyi Chen; Yulan Chen; Yi-Xuan Wang; Wenping Hu

doi:10.1039/C7CC07560J

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Photolysis of polymeric self-assembly controlled by donor–acceptor interaction†

Tingjuan Qian,^a Feiyi Chen,^a Yulan Chen,

*^a Yi-Xuan Wang

*^a and Wenping Hu^a

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* Corresponding authors

^a Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
E-mail: yulan.chen@tju.edu.cn, yx_wang@tju.edu.cn

Abstract

A photodegradable supramolecular polymer was constructed using cucurbit[8]uril (CB[8]) and an alkoxyanthracene guest. The monomeric unit was photostable because of the intramolecular donor–acceptor interaction. However, upon complexation with CB[8], the photolysis of alkoxyanthracene was enhanced, which endowed the supramolecular polymer with great photoreactivity.

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Article information

DOI: https://doi.org/10.1039/C7CC07560J
Article type: Communication
Submitted: 28 Sep 2017
Accepted: 09 Oct 2017
First published: 09 Oct 2017

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Chem. Commun., 2017,53, 11822-11825

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Photolysis of polymeric self-assembly controlled by donor–acceptor interaction

T. Qian, F. Chen, Y. Chen, Y. Wang and W. Hu, Chem. Commun., 2017, 53, 11822 DOI: 10.1039/C7CC07560J

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Chemical Communications

Photolysis of polymeric self-assembly controlled by donor–acceptor interaction†

Abstract

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Photolysis of polymeric self-assembly controlled by donor–acceptor interaction

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