Synthesis of SiC nanonecklaces via chemical vapor deposition in the presence of a catalyst

Abstract

SiC nanonecklaces were synthesized on a large scale on as-prepared Si–SiC ceramic substrates via chemical vapor deposition with ferrocene as a catalyst. Structural, morphological, and elemental analyses showed that the as-synthesized nanonecklaces consisted of 3C–SiC stems up to several hundreds of micrometers in length with diameters of 200–400 nm, and SiO₂ beads with diameters of 0.3–1 μm. On the basis of the experimental and theoretical characterizations, a combination of growth mechanism of a vapor–liquid–solid-stem and modulation-bead was proposed as the growth mode of the SiC nanonecklaces.