Issue 47, 2017
From the journal:

CrystEngComm

Co–Co and Co–Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects†

Bin Fei,a   Jian Zhou,a   Zheng Yan,b   Sergii I. Shylin, ORCID logo cd   Vadim Ksenofontov,c   Il'ya A. Gural'skiy ORCID logo *d  and  Xin Bao ORCID logo *a  

* Corresponding authors

a School of Chemical Engineering, Nanjing University of Science and Technology, 210094 Nanjing, P. R. China
E-mail: baox199@126.com

b College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, P. R. China

c Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg University of Mainz, Duesbergweg 10-14, 55099 Mainz, Germany

d Department of Chemistry, Taras Shevchenko National University of Kyiv, 64 Volodymyrska St., Kyiv 01601, Ukraine
E-mail: illia.guralskyi@univ.kiev.ua

Abstract

A pentanuclear CoII–CoIII cluster complex has been developed by a solvothermal synthesis. Its highly stable metal-mixed iron–cobalt derivatives display robust spin crossover (T1/2 = 268 K) controlled by the degree of substitution.

Graphical abstract: Co–Co and Co–Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects

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Article information

DOI
https://doi.org/10.1039/C7CE01826F
Article type
Communication
Submitted
20 Oct 2017
Accepted
09 Nov 2017
First published
09 Nov 2017

CrystEngComm, 2017,19, 7079-7082

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Co–Co and Co–Fe cyano-bridged pentanuclear clusters based on a methylpyrazinyl-diamine tetradentate ligand: spin crossover and metal substitution effects

B. Fei, J. Zhou, Z. Yan, S. I. Shylin, V. Ksenofontov, I. A. Gural'skiy and X. Bao, CrystEngComm, 2017, 19, 7079 DOI: 10.1039/C7CE01826F

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