Cross-sectional structures of a molecular monolayer nanotube explored with SAXS: evidence for the parallel orientation of the headgroups in asymmetric bolaamphiphiles

Kenta Yoshida; Rintaro Takahashi; Shota Fujii; Naohiro Kameta; Toshimi Shimizu; Kazuo Sakurai

doi:10.1039/C7CP03905K

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Cross-sectional structures of a molecular monolayer nanotube explored with SAXS: evidence for the parallel orientation of the headgroups in asymmetric bolaamphiphiles†

Kenta Yoshida,‡^a Rintaro Takahashi,

‡^a Shota Fujii,^a Naohiro Kameta,

^b Toshimi Shimizu^c and Kazuo Sakurai

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Biochemistry, University of Kitakyushu, 1-1 Hibikino, Wakamatsu-ku, Kitakyushu, Fukuoka 808-0135, Japan
E-mail: sakurai@kitakyu-u.ac.jp

^b Nanomaterials Research Institute, Department of Materials and Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan

^c AIST Fellow, AIST, Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan

Abstract

We investigated the cross-sectional structure of a molecular monolayer nanotube self-assembled from asymmetric bolaamphiphiles having two different hydrophilic headgroups. Small-angle X-ray scattering measurements clarified that the glucose and amino headgroups form the exterior and interior surfaces of the nanotube, respectively.

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Article information

DOI: https://doi.org/10.1039/C7CP03905K
Article type: Communication
Submitted: 12 Jun 2017
Accepted: 17 Aug 2017
First published: 17 Aug 2017

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Phys. Chem. Chem. Phys., 2017,19, 24445-24447

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Cross-sectional structures of a molecular monolayer nanotube explored with SAXS: evidence for the parallel orientation of the headgroups in asymmetric bolaamphiphiles

K. Yoshida, R. Takahashi, S. Fujii, N. Kameta, T. Shimizu and K. Sakurai, Phys. Chem. Chem. Phys., 2017, 19, 24445 DOI: 10.1039/C7CP03905K

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Physical Chemistry Chemical Physics

Cross-sectional structures of a molecular monolayer nanotube explored with SAXS: evidence for the parallel orientation of the headgroups in asymmetric bolaamphiphiles†

Abstract

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Cross-sectional structures of a molecular monolayer nanotube explored with SAXS: evidence for the parallel orientation of the headgroups in asymmetric bolaamphiphiles

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