Issue 19, 2017
From the journal:

Catalysis Science & Technology

Ni(ii) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization†

Min Jeong Kim,a   Sol Ahn,b   Jigyoung Yi,a   Joseph T. Hupp,c   Justin M. Notestein,b   Omar K. Farha*cd  and  Suk Joong Lee ORCID logo *a  

* Corresponding authors

a Dept. of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-701, Republic of Korea
E-mail: slee1@korea.ac.kr
Tel: (+82 2) 3290 3145

b Dept. of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, IL, USA

c Dept. of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, USA

d Dept. of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia

Abstract

A Ni(II) catalyst incorporated into a new porous organic polymer, Ni(II)-POP-1, is prepared via a click reaction followed by metalation with NiCl2. It shows good catalytic activity for liquid-phase ethylene dimerization in the presence of Et2AlCl as a co-catalyst, generating 1-butene.

Graphical abstract: Ni(ii) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

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Article information

DOI
https://doi.org/10.1039/C7CY01274H
Article type
Communication
Submitted
26 Jun 2017
Accepted
31 Aug 2017
First published
04 Sep 2017

Catal. Sci. Technol., 2017,7, 4351-4354

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Ni(II) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

M. J. Kim, S. Ahn, J. Yi, J. T. Hupp, J. M. Notestein, O. K. Farha and S. J. Lee, Catal. Sci. Technol., 2017, 7, 4351 DOI: 10.1039/C7CY01274H

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