Issue 24, 2017
From the journal:

Catalysis Science & Technology

Iridium(iii)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers†

Regina M. Islamova, ORCID logo *a   Mikhail V. Dobrynin,a   Andrey V. Vlasov,a   Anzhelika A. Eremina,a   Mikhail A. Kinzhalov, ORCID logo a   Ilya E. Kolesnikov,a   Andrey A. Zolotarev,a   Eleonora A. Masloborodovac  and  Konstantin V. Luzyanin ORCID logo *ab  

* Corresponding authors

a Saint Petersburg State University, 7/9, Universitetskaya nab, Saint Petersburg, 199034 Russia
E-mail: r.islamova@spbu.ru

b Department of Chemistry, University of Liverpool, Crown Street, Liverpool L69 7ZD, UK
E-mail: konstantin.luzyanin@liverpool.ac.uk

c Lebedev Research Institute for Synthetic Rubber, Gapsal'skaya, 1, 198035 Saint Petersburg, Russian Federation

Abstract

Cyclometallated iridium(III) complexes with 2-phenylpyridine [Ir(ppy)2(CNR)Cl] (ppy = (2-phenylpyridinato-C2,N), R = Xyl, Mes), [Ir(ppy)2(CNR)2](OTf) (R = Xyl, Mes), and fac-[Ir(ppy)3] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 °C leading to luminescent rubbers.

Graphical abstract: Iridium(iii)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

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Article information

DOI
https://doi.org/10.1039/C7CY02013A
Article type
Communication
Submitted
30 Sep 2017
Accepted
01 Nov 2017
First published
01 Nov 2017
This article is Open Access
Creative Commons BY-NC license

Catal. Sci. Technol., 2017,7, 5843-5846

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Iridium(III)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

R. M. Islamova, M. V. Dobrynin, A. V. Vlasov, A. A. Eremina, M. A. Kinzhalov, I. E. Kolesnikov, A. A. Zolotarev, E. A. Masloborodova and K. V. Luzyanin, Catal. Sci. Technol., 2017, 7, 5843 DOI: 10.1039/C7CY02013A

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