Issue 6, 2017
From the journal:

Dalton Transactions

Anion dependent self-assembly of sandwich 13-metal Ni–Ln nanoclusters with a long-chain Schiff base ligand†

Shiqing Wang,ab   Xiaoping Yang,*ab   Jinjie Qian, ORCID logo ab   Qipeng Li, ORCID logo *c   Zhongning Chen, ORCID logo d   Lijie Zhang,ab   Shaoming Huang,*ab   Chengri Wangab  and  Richard A. Jones ORCID logo *e  

* Corresponding authors

a College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China

b Zhejiang Key Laboratory of Carbon Materials, Wenzhou 325035, China
E-mail: xpyang@wzu.edu.cn, smhuang@wzu.edu.cn
Tel: +86 577 88373064

c College of Chemistry and Life Science, Zhaotong University, Zhaotong, China
E-mail: liqipeng10@mails.ucas.ac.cn

d Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
E-mail: czn@fjirsm.ac.cn

e The University of Texas at Austin, Department of Chemistry, 1 University Station A5300, Austin, Texas, USA
E-mail: rajones@cm.utexas.edu

Abstract

Two classes of Ni–Ln clusters [Ln4Ni3L3(OAc)6(NO3)3(OH)3] (Ln = Gd (1) and Tb (2)) and [Ln6Ni7L6(OAc)12(OH)6](OH)2 (Ln = Gd (3) and Dy (4)) were prepared using a specifically designed Schiff base ligand built around a flexible (CH2)2O(CH2)2O(CH2)2 chain. 1 and 2 exhibit cone-like structures, while 3 and 4 have nanosized sandwich architectures. The structures were studied by single-crystal X-ray diffraction and TEM, and magnetic properties were investigated.

Graphical abstract: Anion dependent self-assembly of sandwich 13-metal Ni–Ln nanoclusters with a long-chain Schiff base ligand

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Article information

DOI
https://doi.org/10.1039/C6DT03830A
Article type
Communication
Submitted
03 Oct 2016
Accepted
11 Jan 2017
First published
11 Jan 2017

Dalton Trans., 2017,46, 1748-1752

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Anion dependent self-assembly of sandwich 13-metal Ni–Ln nanoclusters with a long-chain Schiff base ligand

S. Wang, X. Yang, J. Qian, Q. Li, Z. Chen, L. Zhang, S. Huang, C. Wang and R. A. Jones, Dalton Trans., 2017, 46, 1748 DOI: 10.1039/C6DT03830A

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