{Fe3Nb25} cluster based on an Fe-centred Keggin unit

Zhijie Liang; Ke Wang; Dongdi Zhang; Pengtao Ma; Jingyang Niu; Jingping Wang

doi:10.1039/C6DT04223F

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{Fe₃Nb₂₅} cluster based on an Fe-centred Keggin unit†

Zhijie Liang,^a Ke Wang,^a Dongdi Zhang,^a Pengtao Ma,^a Jingyang Niu

*^a and Jingping Wang*^a

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* Corresponding authors

^a Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, P. R. China
E-mail: jyniu@henu.edu.cn, jpwang@henu.edu.cn
Fax: (+86)371-23886876

Abstract

A new heteropolyniobate, [Fe₃Nb₂₅O₇₆]¹⁸⁻, persists in aqueous solution by means of electrospray ionization mass spectrometry. It has been synthesized and characterized by IR, TGA, EDX-SEM, magnetic and single-crystal X-ray diffraction, and it features an Fe-centred Nb-Keggin unit {Fe₃Nb₁₀}.

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Article information

DOI: https://doi.org/10.1039/C6DT04223F
Article type: Communication
Submitted: 05 Nov 2016
Accepted: 15 Dec 2016
First published: 15 Dec 2016

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Dalton Trans., 2017,46, 1368-1371

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{Fe₃Nb₂₅} cluster based on an Fe-centred Keggin unit

Z. Liang, K. Wang, D. Zhang, P. Ma, J. Niu and J. Wang, Dalton Trans., 2017, 46, 1368 DOI: 10.1039/C6DT04223F

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Dalton Transactions