Chemically reversible binding of H2S to a zinc porphyrin complex: towards implementation of a reversible sensor via a “coordinative-based approach”

Abstract

Binding of hydrogen sulfide (H₂S) to a zinc porphyrin complex and the stabilization of the related zinc hydrosulfido adduct are explored. High-resolution MALDI Fourier transform ion cyclotron resonance mass spectrometry (HR MALDI-FT-ICR) and ¹H NMR experiments provide evidence that HS⁻ coordination occurs at the zinc centre. The coordination of HS⁻ occurs in a reversible manner and modulates fluorescence emission of a tetra(N-methylpyridyl)porphine zinc complex (TMPyPZn). The results highlight the potential of TMPyPZn and related systems for the implementation of fast and simple H₂S sensors via a coordinative-based approach.