Issue 13, 2017
From the journal:

Dalton Transactions

Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materials†

Qingpo Peng,a   Shujun Li, ORCID logo *a   Ruoya Wang,a   Shuxia Liu, ORCID logo b   Linhua Xie,c   Jianxin Zhai,a   Jie Zhang, ORCID logo a   Qianyi Zhaoa  and  Xuenian Chen*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China
E-mail: lisj@htu.edu.cn, xnchen@htu.edu.cn

b Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 130024, PR China

c Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

Abstract

Four lanthanide derivatives of Ta-containing POMs [Ln3(H2O)22][P2W15Ta3O62]·nH2O (Ln = La, 1; Ce, 2; Pr, 3; and Nd, 4) were isolated by the self-assembly of Wells–Dawson type Ta/W mixed-addendum POM and lanthanide ions. Compound 1 showed excellent proton conduction performance at high relative humidities (RHs), with conductivity reaching 1.26 × 10−2 S cm−1 at 95 °C under 98% RH.

Graphical abstract: Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materials

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7DT00091J
Article type
Communication
Submitted
10 Jan 2017
Accepted
16 Feb 2017
First published
20 Feb 2017

Dalton Trans., 2017,46, 4157-4160

Permissions

Request permissions

Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materials

Q. Peng, S. Li, R. Wang, S. Liu, L. Xie, J. Zhai, J. Zhang, Q. Zhao and X. Chen, Dalton Trans., 2017, 46, 4157 DOI: 10.1039/C7DT00091J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements