Issue 15, 2017

A novel naphthalenediimide-based lanthanide–organic framework with polyoxometalate templates exhibiting reversible photochromism

Abstract

The first visible-light-responsive photochromic polyoxometalate-templated lanthanide–organic framework (LOF) has been constructed from a carboxyphenyl-substituted naphthalenediimide (NDI) derivative, which displays an unusual four-fold interpenetration of an srs topological network, featuring a variety of anion–π interactions between polyoxoanions and π-acidic NDI moieties, and undergoes a rapid reversible photochromic transformation upon blue light irradiation.

Graphical abstract: A novel naphthalenediimide-based lanthanide–organic framework with polyoxometalate templates exhibiting reversible photochromism

Supplementary files

Article information

Article type
Communication
Submitted
20 Feb 2017
Accepted
13 Mar 2017
First published
20 Mar 2017

Dalton Trans., 2017,46, 4898-4901

A novel naphthalenediimide-based lanthanide–organic framework with polyoxometalate templates exhibiting reversible photochromism

H. Zhang, J. Liao, W. Yang, X. Wu and C. Lu, Dalton Trans., 2017, 46, 4898 DOI: 10.1039/C7DT00631D

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