New complexes containing N-heterocyclic vinylene-stabilized [B2H5]+ fragments were prepared, and surprisingly it was found that the precursor N-heterocyclic olefins (NHOs) could promote the mild (room temperature) catalytic hydroborylation of ketones and aldehydes. This finding represents an important addition to the burgeoning field of non-metal mediated catalysis.
C. Hering-Junghans, I. C. Watson, M. J. Ferguson, R. McDonald and E. Rivard, Dalton Trans., 2017, 46, 7150 DOI: 10.1039/C7DT01303E
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