Issue 25, 2017

Polymorphism of a chiral iron(ii) complex: spin-crossover and ferroelectric properties

Abstract

Two solvent-free polymorphs of a chiral iron(II) complex have been obtained, and their polymorphism dependent spin-crossover and ferroelectric properties have been demonstrated. Polymorph I shows a gradual spin-crossover behavior, whereas polymorph II remains in a high-spin state but shows a typical ferroelectric feature.

Graphical abstract: Polymorphism of a chiral iron(ii) complex: spin-crossover and ferroelectric properties

Supplementary files

Article information

Article type
Communication
Submitted
05 May 2017
Accepted
26 May 2017
First published
26 May 2017

Dalton Trans., 2017,46, 8004-8008

Polymorphism of a chiral iron(II) complex: spin-crossover and ferroelectric properties

W. Han, L. Qin, C. Pang, C. Cheng, W. Zhu, Z. Li, Z. Li, X. Ren and Z. Gu, Dalton Trans., 2017, 46, 8004 DOI: 10.1039/C7DT01634D

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