Issue 28, 2017
From the journal:

Dalton Transactions

Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly†

Yoshifumi Sasano,a   Nobuhiro Yasudab  and  Hiromitsu Maeda ORCID logo *a  

* Corresponding authors

a Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu 525-8577, Japan
E-mail: maedahir@ph.ritsumei.ac.jp

b Research and Utilization Division, Japan Synchrotron Radiation Research Institute, Sayo 679-5198, Japan

Abstract

The NiII complex of 5-hydroxy-10,15,20-tris(pentafluorophenyl)-porphyrin was synthesized as the precursor of a negatively charged π-electronic system. Deprotonation, which was examined through UV/vis and 1H NMR spectra, provided an anionic species as the building unit of an ion-pairing assembly in combination with an aliphatic cation.

Graphical abstract: Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly

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Article information

DOI
https://doi.org/10.1039/C7DT01635B
Article type
Communication
Submitted
05 May 2017
Accepted
10 May 2017
First published
10 May 2017

Dalton Trans., 2017,46, 8924-8928

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Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly

Y. Sasano, N. Yasuda and H. Maeda, Dalton Trans., 2017, 46, 8924 DOI: 10.1039/C7DT01635B

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