A gigantic polyoxozirconate with visible photoactivity

Tingting Xu; Xudong Hou; Yang Wang; Jun Zhang; Junxiang Zhang; Bo Liu

doi:10.1039/C7DT02013A

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A gigantic polyoxozirconate with visible photoactivity†

Tingting Xu,^a Xudong Hou,^a Yang Wang,^a Jun Zhang,^b Junxiang Zhang^a and Bo Liu

*^a

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* Corresponding authors

^a Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China
E-mail: liuchem@ustc.edu.cn

^b School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei, People's Republic of China

Abstract

We present a gigantic polyoxozirconate nanocluster (Zr₁₈O₂₁(μ₂-OH)₂(OOCPh)₂₈), involving 6, 7 and 8-coordinated Zr atoms. It exhibits visible light driven photocatalytic activity for H₂ evolution. The current results could represent a prelude of polyoxozirconate-based photocatalysis.

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DOI: https://doi.org/10.1039/C7DT02013A
Article type: Communication
Submitted: 02 Jun 2017
Accepted: 07 Jul 2017
First published: 07 Jul 2017

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Dalton Trans., 2017,46, 10185-10188

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A gigantic polyoxozirconate with visible photoactivity

T. Xu, X. Hou, Y. Wang, J. Zhang, J. Zhang and B. Liu, Dalton Trans., 2017, 46, 10185 DOI: 10.1039/C7DT02013A

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Dalton Transactions

A gigantic polyoxozirconate with visible photoactivity†

Abstract

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A gigantic polyoxozirconate with visible photoactivity

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