A photochemically dissociating ligand in Ru(bpy)2(dmphen)Cl2 [bpy = 2,2′-bipyridine; dmphen = 2,9-dimethyl-1,10-phenanthroline] was found to be more cytotoxic on the ML-2 Acute Myeloid Leukemia cell line than Ru(bpy)2(H2O)22+ and prototypical cisplatin. Our findings illustrate the potential potency of diimine ligands in photoactivatable Ru(II) complexes.
D. F. Azar, H. Audi, S. Farhat, M. El-Sibai, R. J. Abi-Habib and R. S. Khnayzer, Dalton Trans., 2017, 46, 11529 DOI: 10.1039/C7DT02255G
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