Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

Takamitsu Fukuda; Shun Onodera; Hirohito Watanabe; Kenji Shirasaki; Akira Fuyuhiro; Tomoo Yamamura; Naoto Ishikawa

doi:10.1039/C7DT02656K

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Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres†

Takamitsu Fukuda,

*^a Shun Onodera,^a Hirohito Watanabe,^b Kenji Shirasaki,^b Akira Fuyuhiro,^a Tomoo Yamamura^b and Naoto Ishikawa

*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
E-mail: tfukuda@chem.sci.osaka-u.ac.jp, iskw@chem.sci.osaka-u.ac.jp
Fax: +81-6-6850-5410
Tel: +81-6-6850-5410

^b Laboratory of Alpha-Ray Emitters, Institute for Material Research, Tohoku University, Sendai 980-8577, Japan

Abstract

Magnetic f–π interactions between localized 4f-electrons and itinerant π-electrons have been observed in a single crystal of bisphthalocyaninato yttrium(III)/terbium(III) tetrafluoroborate ([Pc₂Y_0.95Tb_0.05][BF₄]) by measuring electrical conductivity of the crystal in the presence of an external magnetic field.

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Article information

DOI: https://doi.org/10.1039/C7DT02656K
Article type: Communication
Submitted: 21 Jul 2017
Accepted: 21 Aug 2017
First published: 21 Aug 2017

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Dalton Trans., 2017,46, 12421-12424

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Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

T. Fukuda, S. Onodera, H. Watanabe, K. Shirasaki, A. Fuyuhiro, T. Yamamura and N. Ishikawa, Dalton Trans., 2017, 46, 12421 DOI: 10.1039/C7DT02656K

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Dalton Transactions

Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres†

Abstract

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Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

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