Issue 39, 2017

Polycatenation tuned microporosity of two metal–tris(4′-carboxybiphenyl)amine frameworks with multilayer structures

Abstract

By employing a nanosized tris(4′-carboxybiphenyl)amine ligand to assemble with Zn2+ ions, a novel trilayer network (FIR-37) and an unprecedented 2D → 3D microporous polycatenation framework (FIR-38) based on unusual tetralayers have been synthesized and structurally characterized. FIR-38 shows permanent porosity with a Langmuir surface area of 1408.4 m2 g−1.

Graphical abstract: Polycatenation tuned microporosity of two metal–tris(4′-carboxybiphenyl)amine frameworks with multilayer structures

Supplementary files

Article information

Article type
Communication
Submitted
11 Aug 2017
Accepted
10 Sep 2017
First published
11 Sep 2017

Dalton Trans., 2017,46, 13352-13355

Polycatenation tuned microporosity of two metal–tris(4′-carboxybiphenyl)amine frameworks with multilayer structures

Y. He, L. Yuan and J. Zhang, Dalton Trans., 2017, 46, 13352 DOI: 10.1039/C7DT02976D

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