Issue 38, 2017
From the journal:

Dalton Transactions

Isomerisation, reactivity and coordination chemistry of a new hybrid, multi-functional phosphazane†

Alex J. Plajer,a   Kevin Bold,a   Felix J. Rizzuto,a   Raúl García-Rodríguez, ORCID logo *b   Tanya K. Ronsona  and  Dominic S. Wright ORCID logo *a  

* Corresponding authors

a Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK
E-mail: dsw1000@cam.ac.uk

b GIR MIOMeT-IU Cinquima-Química Inorgánica, Facultad de Ciencias, Campus Miguel, Delibes, Universidad de Valladolid, 47011 Valladolid, Spain
E-mail: raul.garcia.rodriguez@uva.es

Abstract

The unsymmetric PIII/PV cyclodiphosphazane framework [(S[double bond, length as m-dash])(H)P(μ-NtBu)2PNHtBu] (2) provides entry into the mixed chalgogenide dianion [(S)P(μ-NtBu)2P(Se)NtBu]2−, and unique insight into the mechanisms of cis/trans isomerism in phosph(III)- and phosph(V)-azanes.

Graphical abstract: Isomerisation, reactivity and coordination chemistry of a new hybrid, multi-functional phosphazane

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Article information

DOI
https://doi.org/10.1039/C7DT03074F
Article type
Communication
Submitted
18 Aug 2017
Accepted
11 Sep 2017
First published
11 Sep 2017

Dalton Trans., 2017,46, 12775-12779

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Isomerisation, reactivity and coordination chemistry of a new hybrid, multi-functional phosphazane

A. J. Plajer, K. Bold, F. J. Rizzuto, R. García-Rodríguez, T. K. Ronson and D. S. Wright, Dalton Trans., 2017, 46, 12775 DOI: 10.1039/C7DT03074F

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