SMM behaviour and magnetocaloric effect in heterometallic 3d–4f coordination clusters with high azide : metal ratios

Sebastian F. M. Schmidt; Marcel P. Merkel; George E. Kostakis; Gernot Buth; Christopher E. Anson; Annie K. Powell

doi:10.1039/C7DT03149A

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SMM behaviour and magnetocaloric effect in heterometallic 3d–4f coordination clusters with high azide : metal ratios†‡

Sebastian F. M. Schmidt,^a Marcel P. Merkel,^b George E. Kostakis,

^c Gernot Buth,^d Christopher E. Anson^a and Annie K. Powell

*^ab

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, D-76131 Karlsruhe, Germany
E-mail: annie.powell@kit.edu
Fax: +49 721 608 8142
Tel: +49 721 608 2135

^b Institut für Nanotechnologie, Karlsruhe Institute of Technology (KIT), Postfach 3640, D-76021 Karlsruhe, Germany

^c Department of Chemistry, University of Sussex, School of Life Sciences, Arrundel Building 305, UK

^d Institute for Photon Science and Synchrotron Radiation (IPS), Karlsruhe Institute of Technology (KIT), Herrmann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

We present the synthesis and characterization of heterometallic compounds with a very large azide to metal ratio. Their interesting structures give rise to fascinating magnetic properties.

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Article information

DOI: https://doi.org/10.1039/C7DT03149A
Article type: Communication
Submitted: 25 Aug 2017
Accepted: 19 Oct 2017
First published: 19 Oct 2017

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Dalton Trans., 2017,46, 15661-15665

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SMM behaviour and magnetocaloric effect in heterometallic 3d–4f coordination clusters with high azide : metal ratios

S. F. M. Schmidt, M. P. Merkel, G. E. Kostakis, G. Buth, C. E. Anson and A. K. Powell, Dalton Trans., 2017, 46, 15661 DOI: 10.1039/C7DT03149A

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