Issue 45, 2017

The Cu(i)-catalysed Huisgen 1,3-dipolar cycloaddition route to (bio-)organic functionalisation of polyoxovanadates

Abstract

The [V6O13{(OCH2)3CCH2OCH2C[triple bond, length as m-dash]CH}2]2− with two terminal alkyne functionalities exhibits excellent reactivity towards (bio-)organic azides. The designed synthetic protocol for the generation of triazol-modified Lindqvist hexavanadates grants access to bio-“clicked” polyoxometalates with spectroscopically detectable 51V nuclei.

Graphical abstract: The Cu(i)-catalysed Huisgen 1,3-dipolar cycloaddition route to (bio-)organic functionalisation of polyoxovanadates

Supplementary files

Article information

Article type
Communication
Submitted
11 Sep 2017
Accepted
21 Sep 2017
First published
22 Sep 2017

Dalton Trans., 2017,46, 15636-15640

The Cu(I)-catalysed Huisgen 1,3-dipolar cycloaddition route to (bio-)organic functionalisation of polyoxovanadates

O. Linnenberg, A. Kondinski, C. Stöcker and K. Yu. Monakhov, Dalton Trans., 2017, 46, 15636 DOI: 10.1039/C7DT03376A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements