The synthesis and characterization of base-stabilized and base-free pincer-type bis(phosphine)/silylene [P2Si]Ru complexes are reported. The base-free complex readily reduces CO2 and CS2via silylene-assisted hydride transfer, affording structurally distinct products with silicon-to-ruthenium formate and dithioformate bridges.
![Graphical abstract: Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C7DT03659K&imageInfo.ImageIdentifier.Year=2017)
M. T. Whited, J. Zhang, S. Ma, B. D. Nguyen and D. E. Janzen, Dalton Trans., 2017, 46, 14757 DOI: 10.1039/C7DT03659K
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