Issue 5, 2017

Synthesis of (E)-β-iodo vinylsulfones via iodine-promoted iodosulfonylation of alkynes with sodium sulfinates in an aqueous medium at room temperature

Abstract

An efficient molecular iodine-promoted method for the synthesis of (E)-β-iodo vinylsulfones using water as the solvent at room temperature has been developed. This green reaction is fast, operationally simple, environmentally benign and, especially, proceeds under very mild conditions to afford the target products with high regio- and stereoselectivity.

Graphical abstract: Synthesis of (E)-β-iodo vinylsulfones via iodine-promoted iodosulfonylation of alkynes with sodium sulfinates in an aqueous medium at room temperature

Supplementary files

Article information

Article type
Communication
Submitted
08 Dec 2016
Accepted
23 Jan 2017
First published
02 Feb 2017

Green Chem., 2017,19, 1255-1258

Synthesis of (E)-β-iodo vinylsulfones via iodine-promoted iodosulfonylation of alkynes with sodium sulfinates in an aqueous medium at room temperature

Y. Sun, A. Abdukader, D. Lu, H. Zhang and C. Liu, Green Chem., 2017, 19, 1255 DOI: 10.1039/C6GC03387C

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