Permittivity imaged at the nanoscale using tip-enhanced Raman spectroscopy

Abstract

Localized surface plasmon resonances are the dominating contribution to the optical enhancement and the lateral resolution in tip-enhanced Raman spectroscopy. This well studied phenomenon may give access to more information about the sample than the enhanced Raman spectra alone due to its sensitivity to the permittivity of the tip environment. In this work, the effects of the permittivity of the sample on the properties of localized surface plasmon resonance are studied through the amplified signal of the luminescence of gold tips.