Issue 11, 2017
From the journal:

New Journal of Chemistry

New lead(ii) borates in the PbO/PbF2/H3BO3 ternary phase diagram: syntheses and structures of β-Pb6B10O21 and Pb4B8O16†

Lingyun Dong,*a   Liangliang Jiab  and  Lijun Wanga  

* Corresponding authors

a Biology & Chemistry department, Baoding University, 3027 East Qiyi Road, Baoding, China
E-mail: donglingyun1234@163.com

b The Institute of Hydrology and Engineering Geological Prospecting Hebei Geological Mineral Bureau, Shijiazhuang, China

Abstract

Through systematic research on the PbO/PbF2/H3BO3 ternary phase diagram, two new lead(II) borates, β-Pb6B10O21 and Pb4B8O16, were synthesized by a high temperature solution method. The polymerization degree of the B–O network was analyzed with increasing B : Pb ratio.

Graphical abstract: New lead(ii) borates in the PbO/PbF2/H3BO3 ternary phase diagram: syntheses and structures of β-Pb6B10O21 and Pb4B8O16

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Article information

DOI
https://doi.org/10.1039/C7NJ00203C
Article type
Paper
Submitted
17 Jan 2017
Accepted
28 Mar 2017
First published
29 Mar 2017

New J. Chem., 2017,41, 4291-4294

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New lead(II) borates in the PbO/PbF2/H3BO3 ternary phase diagram: syntheses and structures of β-Pb6B10O21 and Pb4B8O16

L. Dong, L. Jia and L. Wang, New J. Chem., 2017, 41, 4291 DOI: 10.1039/C7NJ00203C

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