Oxidation of benzyl alcohol over metal organic frameworks M-BTC (M = Co, Cu, Fe)

Ling Peng; Shujie Wu; Xiaoyuan Yang; Jing Hu; Xiaoran Fu; Min Li; Lu Bai; Qisheng Huo; Jingqi Guan

doi:10.1039/C7NJ00588A

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Oxidation of benzyl alcohol over metal organic frameworks M-BTC (M = Co, Cu, Fe)†

Ling Peng,^a Shujie Wu,^a Xiaoyuan Yang,^a Jing Hu,^a Xiaoran Fu,^a Min Li,^a Lu Bai,^a Qisheng Huo^b and Jingqi Guan

*^a

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* Corresponding authors

^a College of Chemistry, Jilin University, Changchun, P. R. China
E-mail: guanjq@jlu.edu.cn

^b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Abstract

A series of metal organic frameworks (MOFs) with cobalt, copper and iron as central metal atoms and 1,3,5-benzenetricarboxylic acid as a ligand were synthesized (denoted M-BTC) for selective oxidation of benzyl alcohols. High conversion (92.9%) and good selectivity (97.1%) were achieved over Co-BTC with air as the oxidant.

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Article information

DOI: https://doi.org/10.1039/C7NJ00588A
Article type: Letter
Submitted: 19 Feb 2017
Accepted: 18 Mar 2017
First published: 20 Mar 2017

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New J. Chem., 2017,41, 2891-2894

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Oxidation of benzyl alcohol over metal organic frameworks M-BTC (M = Co, Cu, Fe)

L. Peng, S. Wu, X. Yang, J. Hu, X. Fu, M. Li, L. Bai, Q. Huo and J. Guan, New J. Chem., 2017, 41, 2891 DOI: 10.1039/C7NJ00588A

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New Journal of Chemistry

Oxidation of benzyl alcohol over metal organic frameworks M-BTC (M = Co, Cu, Fe)†

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Oxidation of benzyl alcohol over metal organic frameworks M-BTC (M = Co, Cu, Fe)

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