Issue 20, 2017
From the journal:

New Journal of Chemistry

A new system for cyclohexane functionalization employing iron(iii) catalysts and trichloroisocyanuric acid†

Clicia A. Gomes,a   Leonardo M. Lube,b   Christiane Fernandes,a   Roberto W. A. Franco, ORCID logo c   Jackson A. L. C. Resende ORCID logo de  and  Adolfo Horn, Jr. ORCID logo *a  

* Corresponding authors

a Universidade Estadual do Norte Fluminense Darcy Ribeiro, Laboratório de Ciências Químicas, Campos dos Goytacazes, RJ 28013-602, Brazil
E-mail: adolfo@uenf.br

b Instituto Federal Fluminense, Campus Centro, Campos dos Goytacazes, RJ 28013-602, Brazil

c Universidade Estadual do Norte Fluminense Darcy Ribeiro, Laboratório de Ciências Físicas, Campos dos Goytacazes, RJ 28013-602, Brazil

d Universidade Federal Fluminense, Laboratório de Difração de Raios X, 24020-150 Niterói/RJ, Brazil

e Instituto de Ciências Exatas e da Terra, Campus Universitário do Araguaia, Universidade Federal do Mato Grosso, Barra do Garças, MT, Brazil

Abstract

Herein, dinuclear and mononuclear iron complexes were investigated as catalysts in the reaction of cyclohexane chlorination employing trichloroisocyanuric acid as oxidant. At 25 °C, the yields provided by both catalysts were similar (∼8%). However, at 50 °C, the mononuclear catalyst showed a better performance (34.4 ± 1.8%) than the binuclear catalyst (24.4 ± 1.0%).

Graphical abstract: A new system for cyclohexane functionalization employing iron(iii) catalysts and trichloroisocyanuric acid

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Article information

DOI
https://doi.org/10.1039/C7NJ01164D
Article type
Letter
Submitted
07 Apr 2017
Accepted
30 Jul 2017
First published
31 Jul 2017

New J. Chem., 2017,41, 11498-11502

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A new system for cyclohexane functionalization employing iron(III) catalysts and trichloroisocyanuric acid

C. A. Gomes, L. M. Lube, C. Fernandes, R. W. A. Franco, J. A. L. C. Resende and A. Horn, New J. Chem., 2017, 41, 11498 DOI: 10.1039/C7NJ01164D

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