Issue 7, 2017
From the journal:

Nanoscale

Reversible conversion between phosphine protected Au6 and Au8 nanoclusters under oxidative/reductive conditions†

Xiujuan Yang,ab   Xinzhang Lin,b   Chao Liu,b   Ren'an Wu,c   Jinghui Yan*a  and  Jiahui Huang ORCID logo *b  

* Corresponding authors

a School of Chemistry & Environmental Engineering, Changchun University of Science and Technology, Changchun, Jilin, China
E-mail: yjh@cust.edu.cn

b Gold Catalysis Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
E-mail: jiahuihuang@dicp.ac.cn

c Novel Technology for High-Resolution Mass Spectrometry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Abstract

In this study, we found that phosphine protected [Au6(dppp)4]2+ and [Au8(dppp)4Cl2]2+ nanoclusters could be reversibly converted under oxidative/reductive conditions. This work not only provides new insights into the relationship between the [Au6(dppp)4]2+ and [Au8(dppp)4Cl2]2+ nanoclusters, but also offers a novel method for controlling structural evolution of different Au nanoclusters.

Graphical abstract: Reversible conversion between phosphine protected Au6 and Au8 nanoclusters under oxidative/reductive conditions

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Article information

DOI
https://doi.org/10.1039/C6NR09524K
Article type
Communication
Submitted
09 Dec 2016
Accepted
17 Jan 2017
First published
18 Jan 2017

Nanoscale, 2017,9, 2424-2427

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Reversible conversion between phosphine protected Au6 and Au8 nanoclusters under oxidative/reductive conditions

X. Yang, X. Lin, C. Liu, R. Wu, J. Yan and J. Huang, Nanoscale, 2017, 9, 2424 DOI: 10.1039/C6NR09524K

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