From acyclic to cyclic α-amino vinylphosphonates by using ring-closing metathesis

Pauline Adler; Antoine Fadel; Joëlle Prunet; Nicolas Rabasso

doi:10.1039/C6OB02548J

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From acyclic to cyclic α-amino vinylphosphonates by using ring-closing metathesis†

Pauline Adler,^a Antoine Fadel,^a Joëlle Prunet*^b and Nicolas Rabasso*^a

Author affiliations

* Corresponding authors

^a Méthodologie, Synthèse et Molécules Thérapeutiques, ICMMO, UMR CNRS 8182, Bât. 410, Université Paris-Sud, 15 rue Georges Clemenceau, 91405 Orsay Cedex, France
E-mail: nicolas.rabasso@u-psud.fr

^b WestCHEM, School of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow G12 8QQ, UK
E-mail: joelle.prunet@glasgow.ac.uk

Abstract

Acyclic α-amino vinylphosphonates were alkylated through the Mitsunobu reaction then diolefinic compounds hence formed were subjected to RCM. Studies on the scope and limitations of RCM with these sterically hindered α-amino vinylphosphonates are detailed.

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Article information

DOI: https://doi.org/10.1039/C6OB02548J
Article type: Paper
Submitted: 21 Nov 2016
Accepted: 24 Nov 2016
First published: 05 Dec 2016

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Org. Biomol. Chem., 2017,15, 387-395

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From acyclic to cyclic α-amino vinylphosphonates by using ring-closing metathesis

P. Adler, A. Fadel, J. Prunet and N. Rabasso, Org. Biomol. Chem., 2017, 15, 387 DOI: 10.1039/C6OB02548J

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Organic & Biomolecular Chemistry

From acyclic to cyclic α-amino vinylphosphonates by using ring-closing metathesis†

Abstract

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From acyclic to cyclic α-amino vinylphosphonates by using ring-closing metathesis

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