Issue 11, 2017
From the journal:

Organic & Biomolecular Chemistry

Gold/silver-catalyzed controllable regioselective vinylcarbene insertion into O–H bonds†

Guangyang Xu,a   Kai Liu,a   Zhenya Dai*b  and  Jiangtao Sun ORCID logo *a  

* Corresponding authors

a Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology and School of Pharmaceutical Engineering & Life Science, Changzhou University, Changzhou 213164, P. R. China
E-mail: jtsun@cczu.edu.cn, jtsun08@gmail.com
Fax: +86519 86334598
Tel: +86 519 86334597

b School of Pharmacy, China Pharmaceutical University, Nanjing 210009, P. R. China

Abstract

An unprecedented regioselective metallo-vinylcarbene insertion into O–H bonds has been achieved with vinyldiazoacetates and 2-pyridones/benzyl alcohols as ideal substrates, which displayed distinct regioselectivity by employing gold and silver catalytic systems.

Graphical abstract: Gold/silver-catalyzed controllable regioselective vinylcarbene insertion into O–H bonds

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Article information

DOI
https://doi.org/10.1039/C7OB00338B
Article type
Communication
Submitted
13 Feb 2017
Accepted
21 Feb 2017
First published
21 Feb 2017

Org. Biomol. Chem., 2017,15, 2345-2348

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Gold/silver-catalyzed controllable regioselective vinylcarbene insertion into O–H bonds

G. Xu, K. Liu, Z. Dai and J. Sun, Org. Biomol. Chem., 2017, 15, 2345 DOI: 10.1039/C7OB00338B

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