We demonstrated the ruthenium-catalyzed allylic amination of 2,3,3-trifluoroallylic carbonates with several types of amines. The reactions proceeded with several types of amines, and succeeded in obtaining polyfluorinated terminal alkenes possessing branched allylic amines as a single regioisomer.
S. Isobe, S. Terasaki, T. Hanakawa, S. Mizuno and M. Kawatsura, Org. Biomol. Chem., 2017, 15, 2938 DOI: 10.1039/C7OB00514H
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