Issue 39, 2017

Cu/Pd cooperatively catalyzed tandem C–N and C–P bond formation: access to phosphorated 2H-indazoles

Abstract

A novel Cu/Pd cooperatively catalyzed tandem C–N and C–P bond formation reaction between 2-alkynyl azobenzenes and P(O)H compounds has been developed. This reaction provides a convenient approach for the synthesis of various phosphorated 2H-indazoles in moderate to good yields, exhibiting good functional group tolerance and high atom economy.

Graphical abstract: Cu/Pd cooperatively catalyzed tandem C–N and C–P bond formation: access to phosphorated 2H-indazoles

Supplementary files

Article information

Article type
Paper
Submitted
17 Sep 2017
Accepted
18 Sep 2017
First published
18 Sep 2017

Org. Biomol. Chem., 2017,15, 8458-8462

Cu/Pd cooperatively catalyzed tandem C–N and C–P bond formation: access to phosphorated 2H-indazoles

W. Wei, X. Li, M. Gu, H. Yao and A. Lin, Org. Biomol. Chem., 2017, 15, 8458 DOI: 10.1039/C7OB02323E

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