The regioselective C–H amination of quinoline amides (C5) and imidazopyridines (C3) under transition-metal-free conditions at room temperature with a high degree of functional group tolerance is reported. The C–H amination promoted by visible light in the presence of a photocatalyst with a wide range of heteroamines makes the present protocol more sustainable.
S. Samanta, C. Ravi, S. N. Rao, A. Joshi and S. Adimurthy, Org. Biomol. Chem., 2017, 15, 9590 DOI: 10.1039/C7OB02504A
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