Issue 6, 2017

Cross-linked perforated honeycomb membranes with improved mechanical and chemical properties

Abstract

Ultrathin perforated honeycomb-patterned membranes show promise for high-resolution separation, in which the mechanical strength and chemical stability of membranes are very important. Here we report facile and versatile modification methods for preparing cross-linked honeycomb membranes with tunable mechanical and chemical properties. Commercially available polystyrene-b-polyisoprene-b-polystyrene (SIS), which contains double bonds for post modification, together with an amphiphilic block copolymer was utilized as the membrane-forming material. Robust and self-standing honeycomb membranes were obtained by the rapid vapor diffusion cross-linking of S2Cl2 in 5 min. X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray spectroscopy (EDX) results demonstrate effective cross-linking. The cross-linked membranes show excellent resistance to organic solvents and other harsh environments. Water flux measurements indicate that the cross-linked membranes can endure trans-membrane pressure as high as 0.12 MPa. The cross-linked membranes are stable in a wide temperature range. Another cross-linking method based on thiol–ene click chemistry is also proved to be able to form robust membranes with both improved stabilities and controllable surface properties. Moreover, the cross-linked perforated honeycomb membranes can be used for separation under higher operation pressure.

Graphical abstract: Cross-linked perforated honeycomb membranes with improved mechanical and chemical properties

Supplementary files

Article information

Article type
Research Article
Submitted
16 Nov 2016
Accepted
07 Dec 2016
First published
07 Dec 2016

Mater. Chem. Front., 2017,1, 1073-1078

Cross-linked perforated honeycomb membranes with improved mechanical and chemical properties

Q. Zhong, L. Zhang, Y. Ou, B. Wu, L. Wan and Z. Xu, Mater. Chem. Front., 2017, 1, 1073 DOI: 10.1039/C6QM00317F

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