Issue 7, 2017

Palladium-catalyzed arene C–H activation/ketone C–H functionalization reaction: route to spirodihydroindenones

Abstract

A novel palladium and norbornene catalyzed arene C–H activation method to synthesize various spirodihydroindenone derivatives was developed. This method produces spirodihydroindenones employing aryl iodides with 2-(2-bromoethyl)-cyclopentanones via a domino reaction, which simplifies the route of building spiro compounds and expands further applications for functional groups selectivity.

Graphical abstract: Palladium-catalyzed arene C–H activation/ketone C–H functionalization reaction: route to spirodihydroindenones

Supplementary files

Article information

Article type
Research Article
Submitted
01 Mar 2017
Accepted
07 Apr 2017
First published
12 Apr 2017

Org. Chem. Front., 2017,4, 1376-1379

Palladium-catalyzed arene C–H activation/ketone C–H functionalization reaction: route to spirodihydroindenones

B. Zhang, H. Hua, L. Gao, C. Liu, Y. Qiu, P. Zhou, Z. Zhou, J. Zhao and Y. Liang, Org. Chem. Front., 2017, 4, 1376 DOI: 10.1039/C7QO00164A

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